Internal Friction and Dynamic Modulus in Metaphosphate Glasses
نویسندگان
چکیده
منابع مشابه
Structural Investigation of Vanadium – Sodium Metaphosphate Glasses
The structure of the glass forming system (V2O5)x – (Na2O · P2O5)(1–x), (x = 0–0.4), has been investigated using Raman spectroscopy. The stretching vibrations of various phosphate groups, connected to phosphorus or vanadium atoms, have been assigned. Variation of the composition leads to structural changes where the sodium metaphosphate -P–O–P-chains break and then reconnect with the oxovanadiu...
متن کاملIonic conductivity and mixed-ion effect in mixed alkali metaphosphate glasses.
In this work, mixed alkali metaphosphate glasses based on K-Na, Rb-Na, Rb-Li, Cs-Na and Cs-Li combinations were studied by differential scanning calorimetry (DSC), complex impedance spectroscopy, and Raman spectroscopy. DSC analyses show that both the glass transition (Tg) and melting temperatures (Tm) exhibit a clear mixed-ion effect. The ionic conductivity shows a strong mixed-ion effect and ...
متن کاملIn Vitro Biocompatibility and Mechanical Performance of Titanium Doped High Calcium Oxide Metaphosphate-Based Glasses
This study challenged to produce phosphate-based glasses (PBG) for the treatment of osseous defects. The glasses contained, among other components, 40 mol% CaO and 1-5 mol% TiO(2). The mechanical performance and in vitro biocompatibility using both human osteosarcoma and primary osteoblasts were carried out. Incorporation of TiO(2) into PBG had no significant effect on strength and modulus. The...
متن کاملDynamic light scattering in mixed alkali metaphosphate glass forming liquids.
We report the first ever photon correlation spectroscopy performed on single alkali and mixed alkali metaphosphate glasses at refractory temperatures above the glass transition. We find not only a significant decrease in the glass transition temperature but also a decrease in fragility for the mixed alkali composition as compared with the single akali glasses. We argue that structural relaxatio...
متن کاملModifier Interaction and Mixed-Alkali Effect in Bond Constraint Theory Applied to Ternary Alkali Metaphosphate Glasses
Introducing an interaction parameter γ, we implement modifier interaction and the mixed-alkali effect into bond constraint theory and apply this extension for simplistic property prediction on ternary phosphate glasses. The severity of the mixed-alkali effect results from the interplay of two simultaneous contributions: bond constraints on the modifier species soften and stiffen with decreasing...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of the Society of Materials Science, Japan
سال: 2004
ISSN: 1880-7488,0514-5163
DOI: 10.2472/jsms.53.444